Seems you can store shedloads of hydrogen in aromatic Iridium sandwiches using formic acid as an intermediary:
.. The resulting iridium compound is an organometallic “half-sandwich complex.” The “bread” is a ring of five or six atoms of carbon that can have various extensions attached (these structures are known as “aromatic rings” even though they do not always have an odor). The “meat” is the iridium atom. A full-sandwich complex consists of two such rings with a metal atom in between.
These iridium half sandwiches can combine carbon dioxide and hydrogen to store the fuel as a safe intermediate—formic acid—and then break apart that intermediate to regenerate hydrogen. Even better, they are capable of running the reaction both ways at room temperature. “A reversible catalytic system that could store hydrogen as formic acid and release it when you need it, and store it back again using CO2, that could be really useful,” Bowring says.
That’s an understatement. The Japanese chemists who filed a patent application for the catalysts described them as “epoch-making.”
Iridium sandwiches significantly reduce the amount of energy required to generate hydrogen and make it possible to store the fuel in the form of the relatively benign formic acid. As an added bonus, one of the feedstocks for the process is carbon dioxide. ..
These iridium half sandwiches can combine carbon dioxide and hydrogen to store the fuel as a safe intermediate—formic acid—and then break apart that intermediate to regenerate hydrogen. Even better, they are capable of running the reaction both ways at room temperature. “A reversible catalytic system that could store hydrogen as formic acid and release it when you need it, and store it back again using CO2, that could be really useful,” Bowring says.
That’s an understatement. The Japanese chemists who filed a patent application for the catalysts described them as “epoch-making.”
Iridium sandwiches significantly reduce the amount of energy required to generate hydrogen and make it possible to store the fuel in the form of the relatively benign formic acid. As an added bonus, one of the feedstocks for the process is carbon dioxide. ..
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