You'll find answers to your questions within the CUK website. Because almost every question you asked will have the regulars frothing at the mouth I'm going to take the unusual step of locking this thread.
On the right you'll find CUK Navigation. >>>>>>>>>
Look down and you'll come to the First Timers section. Have a read through there.
Basic expenses questions answered here: Contractor Expenses - How to claim Travel and other expenses via Limited Company or Umbrella
Then pay particular attention to IR35.
And here are the rules when using company credit cards: http://www.hmrc.gov.uk/payerti/exb/a-z/c/cards.htm
If you go into the Accounting/Legal forum you'll discover the thread Basic advice when running your own contractor business.
Guide to Contracts also has some good articles.
And finally - accountant recommendations - Ta-da!

Happy reading!

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