So if the dividend is paid net, does that mean the company pays the tax just like with PAYE?
In your hands, dividends are treated as though they have already been taxed at 10%. (It is completely irrelevant what tax the company actually paid on profits.) Dividends are taxed at 10% for basic rate taxpayers and 32.5% for higher-rate payers. A basic rate payer is taxed at £1 on each £9 of dividend received, but is regarded as having already paid £1, so has no net tax to pay. A higher rate payer has to pay tax of £3.25 for each £9 received, is regarded as having already paid £1, therefore only has another £2.25 to pay.
Legal dividends can only be paid out of the after-tax money in the company.
If you cannot prove that you knew at the time you declared a dividend that you could afford if out of profits after corporation tax, HMRC may regard it as illegal and tax it as salary. Similarly, if you have not documented it properly with minutes of the meeting at which it was declared they may decide it was an illegal dividend and tax it as salary. If you only realise the need for minutes when you're inspected, and try to pass off back-dated minutes as having been produced at the time, that is a criminal offense for which people have been sent to jail in the past. Do not assume your "full service" accountant produces these minutes, apparently this mistaken assumption is the most common reason people get into trouble with this.
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