There have been questions about whether the amount of CO2 released from the oceans is greater than amounts released by man, and the argument against the question would work against the idea of volcanic emissions.
Basically, the argument is this:
Carbon has three isotopes: C14 which has a half-life of ~5700 years and is replenished in the atmoshere by cosmic rays, and C13 and C12 which are stable. The photosynthetic process tends to prefer CO2 with a C12 atom.
The amount of CO2 in the atmosphere has increased from ~280ppm to nearly 380ppm in the last 150 years. The ratio of C12 to C13 in the atmosphere has also increased in the same time (I didn't see any actual figures, and I didn't see any figures about how much the photosynthetic process "prefers" C12 to C13/C14 either). Since both fossil fuels and wood have more C12 than the general atmosphere, and the C12/C13 ratio has increased along with increases of atmospheric CO2, this suggests that the increase comes from burning fossil fuels and non-fossil fuels, not the ocean or volcanoes. (http://www.realclimate.org/index.php?p=87)
Also, The Lone Gunman had a go at the article linked in the first post about CO2 emissions from volcanoes being "uncertain". Well, just about every scientific measurement has a degree of uncertainty. But the article states an estimate of CO2 released from volcanoes globally (both surface and underwater) and while it concedes the estimate is conservative, it is 150 times less than the amount released by man. It would have to be pretty damn uncertain to compare to that.
Basically, the argument is this:
Carbon has three isotopes: C14 which has a half-life of ~5700 years and is replenished in the atmoshere by cosmic rays, and C13 and C12 which are stable. The photosynthetic process tends to prefer CO2 with a C12 atom.
The amount of CO2 in the atmosphere has increased from ~280ppm to nearly 380ppm in the last 150 years. The ratio of C12 to C13 in the atmosphere has also increased in the same time (I didn't see any actual figures, and I didn't see any figures about how much the photosynthetic process "prefers" C12 to C13/C14 either). Since both fossil fuels and wood have more C12 than the general atmosphere, and the C12/C13 ratio has increased along with increases of atmospheric CO2, this suggests that the increase comes from burning fossil fuels and non-fossil fuels, not the ocean or volcanoes. (http://www.realclimate.org/index.php?p=87)
Also, The Lone Gunman had a go at the article linked in the first post about CO2 emissions from volcanoes being "uncertain". Well, just about every scientific measurement has a degree of uncertainty. But the article states an estimate of CO2 released from volcanoes globally (both surface and underwater) and while it concedes the estimate is conservative, it is 150 times less than the amount released by man. It would have to be pretty damn uncertain to compare to that.
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